During ISL mining, water is pumped to the surface from production wells that contain uranium in very low concentrations, on the order of parts per million concentrations. The next step in the ISL process is to extract the uranium dicarbonate. Extraction is done by chemically exchanging ions inside a processing facility. "The ion exchange process is very analogous to a home Culligan® water softener," Anthony revealed. "It removes hardness or calcium from the water by replacing it with sodium, using ion exchange resins. If you go to Lowe's or Home Depot, and buy a water softener, you basically have a home version of a uranium extraction plant." The main difference is your water softener will have a cation exchanger. "For a uranium plant to function properly, you need to use an anion exchange resin, which is specifically designed to load uranium," Anthony clarified.
And what is this magical "ion exchange resin"? The resin is comprised of little polymer beads, which are charged particles having an affinity for uranium anions. "There are literally millions of these small resin beads in a vessel, which can adsorb low concentration of uranium in solution," said Anthony. Adsorption is when something is attracted to something else or clings to it, like static electricity.
Why do you have to process uranium like this? "In essence, the ion exchange process is a beneficiation (reduction) process that concentrates large volumes of low concentrate uranium solution into a much smaller volume containing a much higher concentration of uranium," said Anthony. In other words, the beneficiation is just concentrating the uranium from the large volume of water in which it is mined into a more compact form. The preferred means is through an ion exchange.
Anthony gave a real-life example of the beneficiation process, "Three million gallons of wellfield solution containing dilute concentrations of uranium, of 100 parts per million minus 0.10 grams/liter, is passed through a bed of ion exchange resin. This might take 24 hours to achieve if the solution is flowing at 2,500 gallons per minute. After this length of time, the resin becomes loaded with approximately 2,500 pounds of uranium."
STRIPPING THE URANIUM
Stripping the uranium is called the elution process. This is done through a chemical exchange of positively and negatively charged ions. Resins are classified by the charge on the active sites. "The active sites on the resin are positively charged for anion resins and negatively charged for cation resins," Norris enlightened us. "The resin's ability to extract chemical ions from a solution is derived from what's called an active site," he continued. "In our case, chloride ions obtained from ordinary tale salt are used to stabilize or temporarily neutralize this positively charged active site." The negatively charged chloride ion sticks to the positively charged site, held in place by what Norris called "electrostatic forces." When the negatively charged ions, such as uranyl dicarbonate, are placed in contact with the solution, it will kick off the chloride and replace that with the uranyl dicarbonate.
That was the chemistry lesson. Anthony summed it up in a nutshell, "They just displace it. There's a greater affinity for the chloride ion to the resin than there is for the uranium. So, the uranium is stripped from the resin bed." The processing facility chemically strips the loaded uranium from the resin by soaking the entire package of uranium-laden resin in a salt bath solution. "The volume of salt solution is on the order of 10,000 gallons resulting in a solution concentration of 30 grams/liter uranium," Anthony said, describing the process of how the uranium becomes concentrated. "The stripped uranium solution concentration is magnified 300 times more than the wellfield solution," he informed us. "The concentration level can now be economically processed for recovery: precipitation, dewatering, drying and drumming for a nuclear facility."
